Abnormal Behavior of the Activation Energy of a Nematic Liquid Crystal in Nonpolar Solvent Benzene

Shyamal K Kudu

Published on: 2023-05-23

Abstract

Temperature and frequency dependent dielectric measurements were performed for investigating the phase transition and the dynamics in 5CB liquid crystal in benzene. In both nematic and isotropic phases, two relaxation processes reflecting rotations around the short and long molecule axes were found. Because of the substantial limitations in the crystalline phase, the shorter relaxation time gained in the crystalline phase is larger than that achieved in the nematic phase. Surprisingly, aberrant isotropic phase behavior was detected, indicating the presence of local structure in the mixture. Significant variation in the activation energy was also observed.

Keywords

Nematic liquid crystal; Dielectric relaxation; Activation energy

Introduction

Because of the extraordinary uses of liquid crystals (LCs), the liquid-crystalline phase has garnered considerable attention [1,2]. Colloidal dispersion containing anisometric compounds (colloidal rods and discs) also have a liquid-crystalline phase. [3]. In 1949, Onsagar [4,5] predicted theoretically the isotropic-nematic phase diagram on lyotropic liquid crystals (LLC) that consists of a solution of hard rods. Only a few works have been reported on the solution properties of liquid crystals. According to Jákli et al. [6], the isotropic-B7 phase transition temperature was dropped from 130°C to 70°C for just 15% of the solvent (p-xylene), and the ‘electro-optical switching’ domain was increased from 1-2°C to over 50°C. Jad?yn and co-workers [7] found the pretranslational critical-like behavior in the mixtures of thermotropic liquid crystal (7CB) with non-mesomorphic compounds (CCl4 and 7CP). Chen and Nozaki [8] observed the 6CB microcrystal from the 6CB/ethanol matrix. We also observed the nematic phase [9] at high volume fraction of 5CB of the 5CB/benzene mixtures, which was correlated with the Onsagar’s theory. It is also possible to study the dynamics of such molecules at the molecular level. So, it turns out that the dispersion of LCs is of great significance not only for the practical applications but also for the basic physical research.

The goal of this research is to investigate the dynamics of a nematic liquid crystal (NLC) molecule in benzene, a nonpolar solvent. The phase transitions and relaxation mechanism of an NLC mixed with benzene were investigated using the broadband dielectric spectroscopic (BDS) approach.

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